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Schrödinger's wave equation (Definition)

The Schrödinger wave equation is considered the most basic equation of non-relativistic quantum mechanics. In three spatial dimensions (that is, in $\mathbb{R}^3$ ) and for a single particle of mass $m$ , moving in a field of potential energy $V$ , the equation is $$ i \hbar\, \frac{\partial}{\partial t}\,\Psi(\vect r, t) = - \frac{\hbar^2}{2m}\cdot \triangle\, \Psi(\vect r, t) + V(\vect r, t)\, \Psi(\vect r, t), $$ where $\vect r := (x,y,z)$ is the position vector, $\hbar=h(2\pi)^{-1}$ , $h$ is Planck's constant, $\triangle$ denotes the Laplacian and $V(\vect r, t)$ is the value of the potential energy at point $\vect r$ and time $t$ . This equation is a second order homogeneous partial differential equation which is used to determine $\Psi$ , the so-called time-dependent wave function, a complex function which describes the state of a physical system at a certain point $\vect r$ and a time $t$ ($\Psi$ is thus a function of 4 variables: $x,y,z$ and $t$ ). The right hand side of the equation represents in fact the Hamiltonian operator (or energy operator) $H\Psi(\vect r, t)$ , which is represented here as the sum of the kinetic energy and potential energy operators. Informally, a wave function encodes all the information that can be known about a certain quantum mechanical system (such as a particle). The function's main interpretation is that of a position probability density for the particle 1 (or system) it describes, that is, if $P(\vect r, t)$ is the probability that the particle is at position $\vect r$ at time $t,$ then an important postulate of M. Born states that $P(\vect r, t) = |\Psi(\vect r, t)|^2$ .

An example of a (relatively simple) solution of the equation is given by the wave function of an arbitrary (non-relativistic) free 2 particle (described by a wave packet which is obtained by superposition of fixed momentum solutions of the equation). This wave function is given by: $$ \Psi(\vect r, t) = \int_{\mathcal{K}} A(\vect k) e^{i(\vect k\cdot \vect r - \hbar\vect{k}^2(2m)^{-1}\,t)}\,d\vect k $$ where $\vect k$ is the wave vector and $\mathcal{K}$ is the set of all values taken by $\vect k.$ For a free particle, the equation becomes $$ i \hbar\, \frac{\partial}{\partial t}\,\Psi(\vect r, t) = - \frac{\hbar^2}{2m}\cdot \triangle\, \Psi(\vect r, t $$ and it is easy to check that the aforementioned wave function is a solution.

An important special case is that when the energy $E$ of the system does not depend on time, i.e. $H\Psi = E\Psi$ , which gives rise to the time-independent Schrödinger equation: $$ E\Psi(\vect r) = - \frac{\hbar^2}{2m}\cdot \triangle\, \Psi(\vect r) + V(\vect r)\, \Psi(\vect r). $$

There are a number of generalizations of the Schrödinger equation, mostly in order to take into account special relativity, such as the Dirac equation (which describes a spin-$\frac{1}{2}$ particle with mass) or the Klein-Gordon equation (describing spin-$0$ particles).



Footnotes

... particle1
This is in fact a little imprecise since the wave function is, in a way, a statistical tool: it describes a large number of identical and identically prepared systems. We speak of the wave function of one particle for convenience.
... free2
By free particle, we imply that the field of potential energy $V$ is everywhere $0.$



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"Schrödinger's wave equation" is owned by Cosmin. [ full author list (4) | owner history (2) ]
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See Also: Schrödinger operator, Hamiltonian operator, quantization, Dirac equation, Klein-Gordon equation, Pauli matrices, d'Alembert and D. Bernoulli solutions of wave equation

Other names:  Schrödinger's equation, time-independent Schrödinger wave equation
Also defines:  wave function
Keywords:  quantum mechanics, wave equation, partial differential equation
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Cross-references: Klein-Gordon equation, Dirac equation, vector, imply, solution, induces, postulate, number, interpretation, operator, right hand side, variables, complex function, partial differential equation, homogeneous, second order, point, Laplacian, position vector, dimensions, equation
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This is version 22 of Schrödinger's wave equation, born on 2005-02-16, modified 2008-08-09.
Object id is 6756, canonical name is SchrodingersWaveEquation.
Accessed 11245 times total.

Classification:
AMS MSC35Q40 (Partial differential equations :: Equations of mathematical physics and other areas of application :: Equations from quantum mechanics)
 81Q05 (Quantum theory :: General mathematical topics and methods in quantum theory :: Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other quantum-mechanical equations)

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