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Version 17 |
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{\em Definition 0.1:}
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{\em Definition 01:}
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| The Hamiltonian operator \textbf{H} introduced in quantum mechanics by Schr\"odinger (and thus sometimes also called the |
The Hamiltonian operator \textbf{H} introduced in quantum mechanics by Schr\"odinger (and thus sometimes also called the |
| \emph{Schr\"odinger operator}) on the Hilbert space $L^2(\Rset^n)$ is given by the action: |
\emph{Schr\"odinger operator}) on the Hilbert space $L^2(\Rset^n)$ is given by the action: |
| \[ |
\[ |
| \psi \mapsto [-\nabla^2 +V(x)]\psi, \quad\psi\in L^2(\Rset^n), |
\psi \mapsto [-\nabla^2 +V(x)]\psi, \quad\psi\in L^2(\Rset^n), |
| \] |
\] |
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| The operator defined above $[-\nabla^2 +V(x)]$ , for a potential function $V(x)$ specified as the real-valued function $V\colon \Rset^n \to \Rset$ is called the {\em Hamiltonian operator}, \textbf{H}, and only very rarely the {\em Schr\"odinger operator}. The energy conservation (quantum) law written with the operator \textbf{H} as the |
The operator defined above $[-\nabla^2 +V(x)]$ , for a potential function $V(x)$ specified as the real-valued function $V\colon \Rset^n \to \Rset$ is called the {\em Hamiltonian operator}, \textbf{H}, and only very rarely the {\em Schr\"odinger operator}. The energy conservation (quantum) law written with the operator \textbf{H} as the |
| Schr\"odinger equation is fundamental in quantum mechanics and is perhaps the most utilized, mathematical computation device in quantum mechanics of systems with a finite number of degrees of freedom. There is also, however, the alternative approach in the Heisenberg picture, or formulation, in which the observable and other operators are time-dependent whereas the state vectors $\psi$ are time-independent, which reverses the time dependences betwen operators and state vectors from the more popular Schr\"odinger formulation. Other formulations of quantum theories occur in |
Schr\"odinger equation is fundamental in quantum mechanics and is perhaps the most utilized, mathematical computation device in quantum mechanics of systems with a finite number of degrees of freedom. There is also, however, the alternative approach in the Heisenberg picture, or formulation, in which the observable and other operators are time-dependent whereas the state vectors $\psi$ are time-independent, which reverses the time dependences betwen operators and state vectors from the more popular Schr\"odinger formulation. Other formulations of quantum theories occur in |
| quantum field theories (QFT), such as QED (quantum electrodynamics) and QCD (quantum chromodynamics). |
quantum field theories (QFT), such as QED (quantum electrodynamics) and QCD (quantum chromodynamics). |
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| Although the two formulations, or pictures, are unitarily (or mathematically) equivalent, according to Wikipedia, however, the Heisenberg picture is "more natural and fundamental than the Schr\"odinger" formulation because the Lorentz invariance from General Relativity is also encountered in the Heisenberg picture, |
Although the two formulations, or pictures, are unitarily (or mathematically) equivalent, according to Wikipedia, however, the Heisenberg picture is "more natural and fundamental than the Schr\"odinger" formulation because the Lorentz invariance from General Relativity is also encountered in the Heisenberg picture, |
| and also because there is a `correspondence' between the commutator of an observable operator with the Hamiltonian operator, and the Poisson bracket formulation of classical mechanics. If the state vector $\psi$, or |
and also because there is a `correspondence' between the commutator of an observable operator with the Hamiltonian operator, and the Poisson bracket formulation of classical mechanics. If the state vector $\psi$, or |
| $\left| \psi \right\rangle$ does not change with time as in the Heisenberg picture, then the `equation of motion' |
$\left| \psi \right\rangle$ does not change with time as in the Heisenberg picture, then the `equation of motion' |
| of a (quantum) observable operator is : |
of a (quantum) observable operator is : |
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|
| \[ |
\[ |
| \frac{d}{dt} A_{quantum} = (i\hbar)^{-1}[A,H] + \left(\frac {\partial A}{\partial t}\right)_{classical} |
\frac{d}{dt} A_{quantum} = (i\hbar)^{-1}[A,H] + \left(\frac {\partial A}{\partial t}\right)_{classical} |
| \] |
\] |