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The lexicographic ordering on On$\times$ On, the class of all pairs of ordinals, is a well-order in the broad sense, in that every subclass of On$\times$ On has a least element, as proposition 2 of the parent entry readily shows. However, with this type of ordering, we get initial segments which are not sets. For example, the initial segment of $(1,0)$ consists of all ordinal pairs of the form $(0,\alpha)$ , where $\alpha\in$ On, and is easily seen to be a proper class. So the questions is: is there a way to order On$\times$ On such that every initial segment of On$\times$ On is a set? The answer is yes. The construction of such a well-ordering in the following discussion is what is known as the canonical well-ordering of On$\times$ On.
To begin, let us consider a strictly linearly ordered set $(A,<)$ . We construct a binary relation $\prec$ on $A\times A$ as follows:
 iff 
For example, consider the usual ordering on $\mathbb{Z}$ . Given $(p,q)\in \mathbb{Z}\times \mathbb{Z}$ . Suppose $p\le q$ . Then the set of all $(m,n) \in \mathbb{Z}\times \mathbb{Z}$ such that $(m,n)\prec (p,q)$ is the union of the three pairwise disjoint sets $\lbrace (m,n)\mid \max\lbrace m,n\rbrace < q\rbrace \cup \lbrace (m,q)\mid m < p \rbrace \cup \lbrace (p,n)\mid n < q\rbrace$ .
Proof. It is irreflexive because $(a_1,a_2)$ is never comparable with itself. It is linear because, first of all, given $(a_1,a_2)\ne (b_1,b_2)$ , exactly one of the three conditions is true, and hence either $(a_1,a_2)\prec (b_1,b_2)$ , or $(b_1,b_2)\prec (a_1,a_2)$ . It remains to show that $\prec$ is transitive, suppose $(a_1,a_2)\prec (b_1,b_2)$ and $(b_1,b_2)\prec (c_1,c_2)$ .
The two cases
- $\max \lbrace a_1,a_2\rbrace < \max \lbrace b_1, b_2\rbrace$ and $\max \lbrace b_1,b_2\rbrace \le \max \lbrace c_1, c_2\rbrace$ ,
- $\max \lbrace a_1,a_2\rbrace \le \max \lbrace b_1, b_2\rbrace$ and $\max \lbrace b_1,b_2\rbrace < \max \lbrace c_1, c_2\rbrace$ ,
produce $\max \lbrace a_1,a_2\rbrace < \max \lbrace c_1, c_2\rbrace$ . Now, assume $\max \lbrace a_1,a_2\rbrace = \max \lbrace b_1, b_2\rbrace = \max \lbrace c_1, c_2\rbrace$ , which result in three more cases
- $a_1 < b_1$ and $b_1 \le c_1$ ,
- $a_1 \le b_1$ and $b_1 < c_1$ ,
- $a_1=b_1=c_1$ , and $a_2 < b_2$ and $b_2 < c_2$ ,
the first two produce $a_1 < c_1$ , and the last $a_1=c_1$ and $a_2<c_2$ . In all cases, we get $(a_1,a_2)\prec (c_1,c_2)$ . 
Proposition 2 If $<$ is a well-order on $A$ , then so is $\prec$ on $A\times A$ .
Proof. Let $R\subseteq A\times A$ be non-empty. Let $$B:=\lbrace \max \lbrace b_1,b_2\rbrace \mid (b_1,b_2)\in R\rbrace.$$ Then $\varnothing \ne B \subseteq A$ , and therefore has a least element $b$ , since $<$ is a well-order on $A$ . Next, let $$C:=\lbrace c_1 \mid \max\lbrace c_1, c_2 \rbrace = b, \mbox{ where }(c_1,c_2)\in R \rbrace.$$ Then $C\ne \varnothing$ , and has a least element $c$ . Finally, let $$D:=\lbrace d_2 \mid \max \lbrace c,d_2\rbrace = b, \mbox{ where }(c,d_2)\in R\rbrace.$$ Again, $D\ne \varnothing$ , so has a least element $d$ . So $(c,d)\in R$ . We want to show that $(c,d)$ is the
least element of $R$ .
Pick any $(x,y)\in R$ distinct from $(c,d)$ . Then $\max \lbrace x, y\rbrace \in B$ is at least $b = \max\lbrace c,d\rbrace$ . If $b<\max \lbrace x, y\rbrace$ , then $(c,d) \prec (x,y)$ . Otherwise, $b=\max \lbrace x, y\rbrace$ , so that $x\in C$ is at least $c$ . If $c < x$ , then again we have $(c,d) \prec (x,y)$ . But if $c=x$ , then $y\in D$ , so that $d \le y$ . Since $(x,y)\ne (c,d)$ , and $x=c$ , $y\ne d$ . Therefore $d < y$ , and $(c,d)\prec (x,y)$ as a result.

The ordering relation above can be generalized to arbitrary classes. Since On is well-ordered by $\in$ , the canonical ordering on On$\times$ On is a well-ordering by proposition 2. Moreover,
Proposition 3 Given the canonical ordering $\prec$ on On$\times$ On, every initial segment is a set.
Proof. Given ordinals $\alpha, \beta\in $ On, suppose $\lambda = \max\lbrace \alpha,\beta\rbrace$ . The initial segment of $(\alpha,\beta)$ is the union of the following collections
- $\lbrace (\gamma,\delta)\mid \max\lbrace \gamma,\delta\rbrace < \lambda \rbrace$ , which is a subcollection of $\lambda \times \lambda$ ,
- $\lbrace (\gamma,\delta) \mid \max\lbrace \gamma,\delta\rbrace = \lambda, \mbox{ and }\gamma < \alpha \rbrace$ , which again is a subcollection $\lambda\times \lambda$ , and
- $\lbrace (\alpha,\delta) \mid \max\lbrace \alpha,\delta \rbrace = \lambda, \mbox{ and }\delta < \beta \rbrace$ , which is a subcollection of $\lbrace \alpha \rbrace \times \beta $ .
Since $\lambda\times \lambda$ and $\lbrace \alpha \rbrace \times \beta $ are both sets, so is the initial segment of $(\alpha,\beta)$ . 
Remark. The canonical well-ordering on On$\times$ On can be used to prove a well-known property of alephs: $\aleph_{\alpha} \cdot \aleph_{\alpha} = \aleph_{\alpha}$ , for any ordinal $\alpha$ .
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