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Let $\mathcal{C},\mathcal{D}$ be categories and $(T,S,\nu)$ be an adjunction from $\mathcal{C}$ to $\mathcal{D}$ . For every pair of objects $C\in\mathcal{C}$ and $D\in\mathcal{D}$ , we have a bijection \begin{equation} \nu_{C,D}:\hom_{\mathcal{D}}(T(C),D) \longrightarrow \hom_{\mathcal{C}}(C,S(D)) \end{equation}that is natural in each variable.
If we set $D=T(C)$ , and write $\nu_C$ for $\nu_{C,T(C)}$ , then we get a bijection $$\nu_C:\hom_{\mathcal{D}}(T(C),T(C)) \longrightarrow \hom_{\mathcal{C}}(C,ST(C))$$ where $ST$ is the abbreviation of $S\circ T$ .
As $1_{T(C)}$ is the identity morphism in $\hom_{\mathcal{D}}(T(C),T(C))$ , define \begin{equation} \eta_C:=\nu_C(1_{T(C)}). \end{equation}Note that $\eta_C$ is a morphism in $\mathcal{C}$ from $C$ to $ST(C)$ . Also, naturality in $C$ means that if $f:C'\to C$ and $g:T(C)\to T(C')$ , then \begin{equation} Sg\circ \eta_c \circ f=\nu_{C'}(g\circ Tf). \end{equation}
Proof. Let $Y$ be an object in $\mathcal{D}$ and $f:C\to S(Y)$ a morphism in $\mathcal{C}$ . We want to find a morphism $g:T(C)\to Y$ in $\mathcal{D}$ such that
is a commutative diagram. The existence and uniqueness of $g$ is guaranteed by the bijection $$\nu_{C,Y}:\hom_{\mathcal{D}}(T(C),Y) \longrightarrow \hom_{\mathcal{C}}(C,S(Y)),$$ where $f=\nu_{C,Y}(g)$ , and the commutativity of the triangle above is guaranteed by the naturality in the second variable
where $\hat{g}:=\hom_{\mathcal{D}}(1_{T(C)},g)$ and $\overline{g}:=\hom_{\mathcal{C}}(1_C,S(g))$ , as $$\overline{g}\circ \nu_C(1_{T(C)})=\hom_{\mathcal{C}}(C,S(g))\circ \eta_C=S(g)\circ \eta_C$$ on the one hand, and $$\nu_{C,Y}\circ \hat{g}(1_{T(C)})=\nu_{C,Y}\circ \hom(T(C),g)(1_{T(C)})=\nu_{C,Y}(g\circ 1_{T(C)})=\nu_{C,Y}(g)=f$$ on the other, and the two are equal. 
Definition. The natural transformation $\eta:I_{\mathcal{C}}\dot{\to} ST$ defined above is called the unit of the adjunction $(T,S,\nu)$ from $\mathcal{C}$ to $\mathcal{D}$ .
Dually, one can find a natural transformation $\epsilon:TS \dot{\to} I_{\mathcal{D}}$ called the counit of the adjunction $(T,S,\nu):\mathcal{C}\to\mathcal{D}$ . To do this, set $C=S(D)$ and use equation (1) to get a bijection $\nu_D:=\nu_{S(D),D}$ and subsequently define \begin{equation} \epsilon_D:=\nu_D(1_{S(D)}). \end{equation}As in the previous theorems, one can, by reversing all the arrows, show that $(S(D),\epsilon_D)$ is a universal arrow from $D$ to $T$ , and that $\epsilon$ is indeed a natural transformation from $TS$ to $I_{\mathcal{D}}$ .
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- S. Mac Lane, Categories for the Working Mathematician (2nd edition), Springer-Verlag, 1997.
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