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Let's first prove the second inequality. If is singular, the thesis is trivially verified, since for a Hermitian positive semidefinite matrix the right-hand side is always nonnegative, all the diagonal
entries being nonnegative. Let's thus assume
, which means, being Hermitian positive semidefinite,
. Then no diagonal entry of can be 0 (otherwise, since for a Hermitian positive semidefinite matrix,
,
and
being respectively the minimal and the maximal eigenvalue, this would imply
, that is is singular); for this reason we can define
, with
, since all
. Let's furthermore define . It's easy to check that too is Hermitian positive semidefinite, so its eigenvalues
are all non-negative (actually, since and since is real and diagonal,
; on the other hand, for any
,
). Moreover, we have obviously
so that and, recalling the geometric-arithmetic mean inequality, which holds in this case because the eigenvalues of are all non-negative,
,
and since
, we have the thesis. Since
if and only if
and since in the geometric-arithmetic inequality equality holds if and only if all terms are equal, we must have
, so that
, whence
(
having to be non-negative), and since is Hermitian and hence is diagonalizable, we obtain , and so
. So we can conclude that equality holds if and only if is diagonal.
Let's now derive the more general first inequality. Let be a complex-valued matrix. If is singular, the thesis is trivially verified. Let's thus assume
; then is a Hermitian positive semidefinite matrix (actually,
and, for any
,
). Therefore, the second inequality can be applied to , yielding:

.
As we proved above, for to be equal to
, must be diagonal, which means that
. So we can conclude that equality holds if and only if the rows of are orthogonal. 
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- R. A. Horn, C. R. Johnson, Matrix Analysis, Cambridge University Press, 1985
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